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One of the most popular attractions in a public or private
aquatic facility or health club is the spa,
hot tub or whirlpool bath
which features hot, swirling, water that provides a sense of relaxation,
health and well being.
But this popular attraction has become a major
health
concern for most facilities because of increased risk of bacterial
infection resulting in the common Pseudomonas Aeruginosa, which creates an
uncomfortable skin rash or the more serious Legionella Pneumophila
(Legionnaire's disease) which has been evident on a cruise ship and in
some display and backyard spas.
Dr.
R. Neil Lowry, a Ph.D in inorganic chemistry, is a consultant to the
swimming pool and spa industry and a regular contributor to this
publication. He has written several articles on hot water maintenance and
stresses the importance of using the proper sanitizers for the unique
conditions of spa water, maintaining adequate levels of sanitizers and
chemical parameters for spa water, and most importantly, the regular
dumping of spa water to insure cleanliness.
This article is a synopsis of several articles produced by
Dr. Lowry and should be an easy guideline to the proper maintenance of any
hot water installation.
Sanitizing Chemicals
There are a number of products on the market that will
sanitize water. However, the high temperature and small volume of spa
water makes hot water unique in the required treatment. These two areas of
distinction differentiate spa water from pool water.
A. High Temperatures
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Greater tendency for scale formation
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High TDS (Totally Dissolved Solids) as higher
evaporation rat
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Higher levels of organics from bather
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Faster chemistry
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Pseudomonas growth
B. Small Volumes
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High turnover rate of spa water
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Chemical dosage sensitivity
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Heavy bather load
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Low total reserve of sanitizer
Constant feed of the sanitizer and oxidizer is extremely
important to the cleanliness of spa water.
In hot water, the chemical reaction proceeds twice as fast
for every 10 degrees C that the water is raised.
Spa maintenance staff may
notice that chlorine levels are constantly being depleted and may think
that the hot water is decomposing the chlorine. However, chlorine
residuals are quite stable in clean, hot water which creates no chlorine
demand. The combination of a higher reaction rate in the hot water and the
created chlorine demand, caused by the moving, hot water drawing more
organic materials from the body, creates the conditions that use up the
chlorine at a faster rate, therefore, maintaining chlorine levels through
constant feed, to meet the increased demand, is essential.
There are three products that best suit the spa market for
sanitation. In the chlorine lines there are two products, Lithium
Hypochlorite (a granular chlorine that contains no calcium) and Sodium
Dichloro-s-triazinetrione (a fast dissolving stabilized chlorine granule)
that has the unique property of being
pH neutral. It should be noted that
any chlorine sanitizer has the drawback of forming combined chlorine or
chloramines. Formed by the combination of chlorine and ammonia based
chemicals from bathers, chloramines have the characteristic pungent
chlorine odor coming from heavily used spas. Besides the disagreeable
odor, they are irritants to the eyes and mucous membranes of bathers.
Combined chlorines also are too slow a sanitizer to be effective in spa
waters.
Slow dissolving
Bromine tablets are analogous to chlorine sanitation and have certain
defined advantages when used for spa water sanitation. First, bromamines
have little odor or bather irritation and are good sanitizers themselves.
Second,
bromine residuals are more effective than chlorine over the broad range of
pH values experienced in the small volumes of spa water. Being slow
dissolving, bromine tablets lend themselves to a constant feed system. The
one negative aspect of brominating tablets is that they are an acid feed
sanitizer with a pH of 4.8 which can quickly deplete total
alkalinity and
lower pH.
A second type of bromine utilized in spas is a two part
sanitizer system. This is based on the fact that when bromine is reduced
during sanitation and oxidation, it is converted to a "bromide bank" which
is a concentrated level of bromide ion. This "bank" can be oxidized by
chlorine, ozone or potassium monopersulfate back to the "active" bromine
residual.
Suggested Ranges
Compared to pool parameter values, there are some
significant differences in the levels of spa water parameters. Lower
levels of calcium hardness and pH compensate for the scale formation
tendency of hot water. Sanitizer levels are significantly higher than
pools due to the lack of total sanitizer reserve due to the higher
chlorine demand. Stabilizer levels of 100 ppm are required for most states
and provinces with the exception of Ontario which requires only 60 ppm.
Suggested Ranges For Spa Water Chemical Parameters
Total Alkalinity 80-120 ppm
Calcium Hardness 150-200 ppm
pH 7.2-7.6
Chlorine/Bromine 5.0-10.0 ppm
Stabilizer 100 ppm (max)
It is also recommended that after each period of use, the
level of the sanitizer should be raised to its maximum of 10.0 ppm. This
is to avoid having heavily loaded spa water sitting for periods of time
with a zero sanitizer level. If the water is murky, or if the sanitizer
level is difficult to attain, additional superchlorination may be
required.
Drain The Water
Periodic complete draining of spa water is the most
important component of proper spa water maintenance. High bather loads and
the hot water conditions cannot be handled over long periods of time
without draining the spa. The following is a dumping formula that is in
the guideline: "Recommended Standards for the Operation of Public Spas,"
by the Ministry of Health, Ontario and should be followed.
Number of Days Between Draining Spa = 1/ 3 (volume in US
gals) / Maximum Number of Daily Bathers
or in metric measurement
Number of Days Between Draining Spa = Spa volume in liters / 10 x Maximum
Number of Daily Bathers
Example: If you have 100 people using a 600 gallon spa in a day, the spa
should be dumped every 1 / 3(600) / 100 = 2 days. If this procedure isn't
followed, the spa will become quite unsanitary very shortly.
A key indicator of a spa out of control is the formation
of residual foam when the spa pump is turned off. This is unsanitary as
the surface of the bubbles harbors bacteria which floats on the sanitized
spa water. This bacteria is not destroyed and serves as a constant source
of bacteria inoculation into the spa water.
Foam formation will not occur
if the draining formula is obeyed.
In summary, spa water chemistry differs from pool water
chemistry because of extreme bather loads, propensity for scale formation
and a small total reserve of sanitizer in the hot water. The key to safe
water is the constant feed of a good sanitizer, proper
chemical ranges, and, most
important, the periodic, complete draining of spa water and the refill
with fresh water. In this way you will maintain a healthy, properly
sanitized body of water.
Article derived from Pool & Spa Marketing, April
1998
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